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We measure the CO-to-H₂conversion factor (α_CO) in 37 galaxies at 2 kpc resolution, using the dust surface density inferred from far-infrared emission as a tracer of the gas surface density and assuming a constant dust-to-metal ratio. In total, we have ∼790 and ∼610 independent measurements ofα_COfor CO (2–1) and (1–0), respectively. The mean values forα_{CO (2–1)}andα_{CO (1–0)}are${9.3}_{-5.4}^{+4.6}$and${4.2}_{-2.0}^{+1.9}{M}_{\odot }{\mathrm{pc}}^{-2}{(\mathrm{K}\mathrm{km}{\mathrm{s}}^{-1})}^{-1}$, respectively. The CO-intensity-weighted mean is 5.69 forα_{CO (2–1)}and 3.33 forα_{CO (1–0)}. We examine howα_COscales with several physical quantities, e.g., the star formation rate (SFR), stellar mass, and dust-mass-weighted average interstellar radiation field strength ($\overline{U}$). Among them,$\overline{U}$, Σ_SFR, and the integrated CO intensity (W_CO) have the strongest anticorrelation with spatially resolvedα_CO. We provide linear regression results toα_COfor all quantities tested. At galaxy-integrated scales, we observe significant correlations betweenα_COandW_CO, metallicity,$\overline{U}$, and Σ_SFR. We also find thatα_COin each galaxy decreases with the stellar mass surface density (Σ_⋆) in high-surface-density regions (Σ_⋆≥ 100M_⊙pc⁻²), following the power-law relations${\alpha }_{\mathrm{CO}(2–1)}\propto {\mathrm{\Sigma }}_{\star }^{-0.5}$and${\alpha }_{\mathrm{CO}(1–0)}\propto {\mathrm{\Sigma }}_{\star }^{-0.2}$. The power-law index is insensitive to the assumed dust-to-metal ratio. We interpret the decrease inα_COwith increasing Σ_⋆as a result of higher velocity dispersion compared to isolated, self-gravitating clouds due to the additional gravitational force from stellar sources, which leads to the reduction inα_CO. The decrease inα_COat high Σ_⋆is important for accurately assessing molecular gas content and star formation efficiency in the centers of galaxies, which bridge “Milky Way–like” to “starburst-like” conversion factors.

We present maps tracing the fraction of dust in the form of polycyclic aromatic hydrocarbons (PAHs) in IC 5332, NGC 628, NGC 1365, and NGC 7496 from JWST/MIRI observations. We trace the PAH fraction by combining the F770W (7.7μm) and F1130W (11.3μm) filters to track ionized and neutral PAH emission, respectively, and comparing the PAH emission to F2100W, which traces small, hot dust grains. We find the averageR_PAH= (F770W + F1130W)/F2100W values of 3.3, 4.7, 5.1, and 3.6 in IC 5332, NGC 628, NGC 1365, and NGC 7496, respectively. We find that Hiiregions traced by MUSE Hαshow a systematically low PAH fraction. The PAH fraction remains relatively constant across other galactic environments, with slight variations. We use CO+Hi+Hαto trace the interstellar gas phase and find that the PAH fraction decreases above a value of${\mathrm{I}}_{\mathrm{H}\alpha }/{\mathrm{\Sigma }}_{\mathrm{H}\mathrm{I}+{\mathrm{H}}_2}\sim {10}^{37.5}\mathrm{erg}{\mathrm{s}}^{-1}{\mathrm{kpc}}^{-2}{(M_{\odot }{\mathrm{pc}}^{-2})}^{-1}$in all four galaxies. Radial profiles also show a decreasing PAH fraction with increasing radius, correlated with lower metallicity, in line with previous results showing a strong metallicity dependence to the PAH fraction. Our results suggest that the process of PAH destruction in ionized gas operates similarly across the four targets.

JWST observations of polycyclic aromatic hydrocarbon (PAH) emission provide some of the deepest and highest resolution views of the cold interstellar medium (ISM) in nearby galaxies. If PAHs are well mixed with the atomic and molecular gas and illuminated by the average diffuse interstellar radiation field, PAH emission may provide an approximately linear, high-resolution, high-sensitivity tracer of diffuse gas surface density. We present a pilot study that explores using PAH emission in this way based on Mid-Infrared Instrument observations of IC 5332, NGC 628, NGC 1365, and NGC 7496 from the Physics at High Angular resolution in Nearby GalaxieS-JWST Treasury. Using scaling relationships calibrated in Leroy et al., scaled F1130W provides 10–40 pc resolution and 3σsensitivity of Σ_gas∼ 2M_⊙pc⁻². We characterize the surface densities of structures seen at <7M_⊙pc⁻²in our targets, where we expect the gas to be Hi-dominated. We highlight the existence of filaments, interarm emission, and holes in the diffuse ISM at these low surface densities. Below ∼10M_⊙pc⁻²for NGC 628, NGC 1365, and NGC 7496 the gas distribution shows a “Swiss cheese”-like topology due to holes and bubbles pervading the relatively smooth distribution of the diffuse ISM. Comparing to recent galaxy simulations, we observe similar topology for the low-surface-density gas, though with notable variations between simulations with different setups and resolution. Such a comparison of high-resolution, low-surface-density gas with simulations is not possible with existing atomic and molecular gas maps, highlighting the unique power of JWST maps of PAH emission.

We explore the relationship between mid-infrared (mid-IR) and CO rotational line emission from massive star-forming galaxies, which is one of the tightest scalings in the local universe. We assemble a large set of unresolved and moderately (∼1 kpc) spatially resolved measurements of CO (1–0) and CO (2–1) intensity,I_CO, and mid-IR intensity,I_MIR, at 8, 12, 22, and 24μm. TheI_COversusI_MIRrelationship is reasonably described by a power law with slopes 0.7–1.2 and normalizationI_CO∼ 1 K km s⁻¹atI_MIR∼ 1 MJy sr⁻¹. Both the slopes and intercepts vary systematically with choice of line and band. The comparison between the relations measured for CO (1–0) and CO (2–1) allow us to infer that$R_{21}\propto I_{\mathrm{MIR}}^{0.2}$, in good agreement with other work. The 8μm and 12μm bands, with strong polycyclic aromatic hydrocarbon (PAH) features, show steeper CO versus mid-IR slopes than the 22 and 24μm, consistent with PAH emission arising not just from CO-bright gas but also from atomic or CO-dark gas. The CO-to-mid-IR ratio correlates with global galaxy stellar mass (M_⋆) and anticorrelates with star formation rate/M_⋆. At ∼1 kpc resolution, the first four PHANGS–JWST targets show CO-to-mid-IR relationships that are quantitatively similar to our larger literature sample, including showing the steep CO-to-mid-IR slopes for the JWST PAH-tracing bands, although we caution that these initial data have a small sample size and span a limited range of intensities.

We present a rich, multiwavelength, multiscale database built around the PHANGS–ALMA CO (2 − 1) survey and ancillary data. We use this database to present the distributions of molecular cloud populations and subgalactic environments in 80 PHANGS galaxies, to characterize the relationship between population-averaged cloud properties and host galaxy properties, and to assess key timescales relevant to molecular cloud evolution and star formation. We show that PHANGS probes a wide range of kpc-scale gas, stellar, and star formation rate (SFR) surface densities, as well as orbital velocities and shear. The population-averaged cloud properties in each aperture correlate strongly with both local environmental properties and host galaxy global properties. Leveraging a variable selection analysis, we find that the kpc-scale surface densities of molecular gas and SFR tend to possess the most predictive power for the population-averaged cloud properties. Once their variations are controlled for, galaxy global properties contain little additional information, which implies that the apparent galaxy-to-galaxy variations in cloud populations are likely mediated by kpc-scale environmental conditions. We further estimate a suite of important timescales from our multiwavelength measurements. The cloud-scale freefall time and turbulence crossing time are ∼5–20 Myr, comparable to previous cloud lifetime estimates. The timescales for orbital motion, shearing, and cloud–cloud collisions are longer, ∼100 Myr. The molecular gas depletion time is 1–3 Gyr and shows weak to no correlations with the other timescales in our data. We publish our measurements online, and expect them to have broad utility to future studies of molecular clouds and star formation.